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**El número cuántico secundario**, representado por la letra _'l'_, es uno de los cuatro números cuánticos que describen las propiedades de los electrones en un átomo. Mientras que el número cuántico principal (_'n'_) nos habla del nivel de energía y la distancia promedio del electrón al núcleo, el número cuántico secundario revela la **forma** del orbital atómico y, en cierta medida, su energía. Piensen en _'l'_ como el arquitecto que define la estructura del hogar electrónico de los electrones. Este número toma valores que van desde 0 hasta _n-1_, donde _n_ es el número cuántico principal. Por ejemplo, si _n = 2_, entonces _l_ puede ser 0 o 1. Cada valor de _'l'_ corresponde a una forma diferente de orbital:
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